Metherell, A.J. and Ward, M.D. (2014) Stepwise assembly of an adamantoid Ru4Ag6 cage by control of metal coordination geometry at specific sites. Chemical Communications, 50 (75). 10979 - 10982. ISSN 1359-7345
Abstract
The geometrically pure ‘complex ligand’ fac-[Ru(Lph)3]2+, in which three pendant bidentate binding sites are located on one face of the complex, reacts with Ag(I) ions to form the adamantoid decanuclear cage [{Ru(Lph)3}4Ag6](PF6)14 which contains a 6-coordinate Ru(II) ion at each vertex of a large tetrahedron and a 4-coordinate Ag(I) ion along each edge.
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Copyright, Publisher and Additional Information: | © 2014 The Author(s). This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. | ||||
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Institution: | The University of Sheffield | ||||
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) | ||||
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Depositing User: | Symplectic Sheffield | ||||
Date Deposited: | 03 Mar 2015 14:30 | ||||
Last Modified: | 03 Mar 2015 14:30 | ||||
Published Version: | http://dx.doi.org/10.1039/c4cc05421k | ||||
Status: | Published | ||||
Publisher: | Royal Society of Chemistry | ||||
Refereed: | Yes | ||||
Identification Number: | https://doi.org/10.1039/c4cc05421k |