Rodríguez-Bárzano, A, Blacker, AJ and McGowan, PC (2013) Synthesis and characterisation of tetramethylfulvene complexes of ruthenium. Dalton Transactions: an international journal of inorganic chemistry, 42 (48). 16669 - 16671. ISSN 1477-9226
Abstract
Reactions of [RuCp*Cl2]2 with dibenzoylmethane and triethylamine, in either dichloromethane or toluene, produced the complexes [RuCl(η6-C5Me4CH2)(PhCOCCOPh)] (1) and [RuCl3(η6-C5Me4CH 2)][RuCp*(C6H5CH3)] (2) respectively under mild conditions. Both compounds 1 and 2 are examples of an unusual tetramethylfulvene-ruthenium structure, obtained by deprotonation of the pentamethylcyclopentadienyl ligand, and were characterised by single-crystal X-ray diffraction.
Metadata
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| Dates: |
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| Institution: | The University of Leeds |
| Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) |
| Depositing User: | Symplectic Publications |
| Date Deposited: | 21 Oct 2014 08:45 |
| Last Modified: | 21 Oct 2014 08:45 |
| Published Version: | http://dx.doi.org/10.1039/c3dt52747f |
| Status: | Published |
| Publisher: | Royal Society of Chemistry |
| Identification Number: | https://doi.org/10.1039/c3dt52747f |
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