Townrow, Oliver P.E., Chung, Cheuk, Macgregor, Stuart A. et al. (2 more authors) (2020) A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes. Journal of the American Chemical Society. pp. 18330-18335. ISSN 1520-5126
Abstract
We report on the synthesis of an alkane-soluble Zintl cluster, [η4-Ge9(Hyp)3]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst.
Metadata
Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2020, The Author(s). | ||||
Dates: |
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Institution: | The University of York | ||||
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) | ||||
Funding Information: |
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Depositing User: | Pure (York) | ||||
Date Deposited: | 15 Oct 2020 09:10 | ||||
Last Modified: | 06 Dec 2023 13:55 | ||||
Published Version: | https://doi.org/10.1021/jacs.0c09742 | ||||
Status: | Published | ||||
Refereed: | Yes | ||||
Identification Number: | https://doi.org/10.1021/jacs.0c09742 | ||||
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