Dennis, F., Robertson, C. and Partridge, B. orcid.org/0000-0002-8550-9994 (2020) Nickel-catalysed allylboration of aldehydes. Synthesis, 52 (13). pp. 1903-1914. ISSN: 0039-7881
Abstract
A nickel catalyst for the allylboration of aldehydes is reported, facilitating the preparation of homoallylic alcohols in high diastereoselectivity. The observed diastereoselectivities and NMR experiments suggest that allylation occurs through a well-defined six-membered transition state, with nickel acting as a Lewis acid.
Metadata
| Item Type: | Article |
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| Authors/Creators: |
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| Copyright, Publisher and Additional Information: | © 2020 Georg Thieme Verlag Stuttgart. This is an author-produced version of a paper subsequently published in Synthesis. Uploaded in accordance with the publisher's self-archiving policy. |
| Keywords: | allylboration; boronic esters; catalysis; homoallylic alcohols; nickel |
| Dates: |
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| Institution: | The University of Sheffield |
| Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
| Date Deposited: | 09 Jul 2020 12:57 |
| Last Modified: | 08 Oct 2025 18:16 |
| Status: | Published |
| Publisher: | Thieme Publishing |
| Refereed: | Yes |
| Identification Number: | 10.1055/s-0039-1690091 |
| Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:163076 |

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