Tumanov, SV, Veber, SL, Greatorex, S et al. (2 more authors) (2018) Interplay between Dopant Species and a Spin-Crossover Host Lattice during Light-Induced Excited-Spin-State Trapping Probed by Electron Paramagnetic Resonance Spectroscopy. Inorganic Chemistry, 57 (15). pp. 8709-8713. ISSN 0020-1669
Abstract
Q-band electron paramagnetic resonance (EPR) data conclusively demonstrate that the iron and cobalt centers in the solid solution [Fe(bpp)₂]₀.₉₇[Co(terpy)₂]₀.₀₃[BF₄]₂ (bpp = 2,6-dipyrazol-1-ylpyridine) undergo allosteric spin-state switching during light-induced excited-spin-state trapping (LIESST) at 20 K and thermal relaxation around 80 K. EPR of [Cu(terpy)₂]²⁺ and [Cu(bpp)₂]²⁺, doped into the same host lattice, also indicates expansion of the copper coordination sphere during LIESST excitation.
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Copyright, Publisher and Additional Information: | © 2018 American Chemical Society. This is an author produced version of a paper published in Inorganic Chemistry. Uploaded in accordance with the publisher's self-archiving policy. | ||||
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Institution: | The University of Leeds | ||||
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Inorganic Chemistry (Leeds) | ||||
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Depositing User: | Symplectic Publications | ||||
Date Deposited: | 09 Jul 2018 11:02 | ||||
Last Modified: | 11 Jul 2019 00:40 | ||||
Status: | Published | ||||
Publisher: | American Chemical Society | ||||
Identification Number: | https://doi.org/10.1021/acs.inorgchem.8b01096 |