The retention and release of flammable gases from corroded Magnox sludge waste at Sellafield, UK and secondary reprocessing waste at Hanford, USA has significant economic and safety implications for decommissioning various nuclear legacy buildings. Magnesium hydroxide is the primary precipitation product from the corrosion of first generation nuclear fuel in the UK, with hydrogen gas produced as a reaction by-product. Depending on the bed microstructure, wettability and shear yield stress behaviour, some consolidated sediments of these corrosion products are able to trap a substantial volume of gas, sufficient in some instances to become buoyant with respect to a water supernatant, resulting in an undesirable upward transfer of radioactive material from the consolidated bed. These phenomena are investigated using the decomposition of hydrogen peroxide to produce oxygen bubbles within magnesium hydroxide soft sediments at laboratory scale. X-ray tomography analysis showed that high strength sediments of 1112 Pa shear yield stress supported much larger bubbles up to 20 mm equivalent spherical diameter than beds in the 7-234 Pa range, which demonstrated almost identical bubble size distributions across the range. The largest retained bubbles became progressively more distorted with increased sediment strength until the lateral cracks consistent with tensile fracture became apparent in the 1112 Pa bed. These cracks significantly limited the capacity for bed swell as gas diffusion along the cracks to the container walls provided a continuous escape route. The capacity for gas retention was also substantially reduced when gas generation was not homogeneous through the bed as localised gas generation promoted the formation of low density pathways, rich with micro-bubbles, which enable gas transport through the bed.
CORE (COnnecting REpositories)
CORE (COnnecting REpositories)