Robshaw, T.J. orcid.org/0000-0002-9816-8236, Bonser, K., Coxhill, G. et al. (2 more authors) (2020) Development of a combined leaching and ion-exchange system for valorisation of spent potlining waste. Waste and Biomass Valorization, 11 (10). pp. 5467-5481. ISSN 1877-2641
Abstract
This work aims to contribute to addressing the global challenge of recycling and valorising spent potlining; a hazardous solid waste product of the aluminium smelting industry. This has been achieved using a simple two-step chemical leaching treatment of the waste, using dilute lixiviants, namely NaOH, H2O2 and H2SO4, and at ambient temperature. The potlining and resulting leachate were characterised by spectroscopy and microscopy to determine the success of the treatment, as well as the morphology and mineralogy of the solid waste. This confirmed that the potlining samples were a mixture of contaminated graphite and refractory materials, with high variability of composition. A large quantity of fluoride was solublised by the leaching process, as well as numerous metals, some of them toxic. The acidic and caustic leachates were combined and the aluminium and fluoride components were selectively extracted, using a modified ion-exchange resin, in fixed-bed column experiments. The resin performed above expectations, based on previous studies, which used a simulant feed, extracting fluoride efficiently from leachates of significantly different compositions. Finally, the fluoride and aluminium were coeluted from the column, using NaOH as the eluent, creating an enriched aqueous stream, relatively free from contaminants, from which recovery of synthetic cryolite can be attempted. Overall, the study accomplished several steps in the development of a fully-realised spent potlining treatment system.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2020 The Author(s). This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made (http://creativecommons.org/licenses/by/4.0/). |
Keywords: | Spent potlining; Leaching; Ion-exchange; Fluoride; Aluminium; Resource recovery |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Chemical and Biological Engineering (Sheffield) The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
Funding Information: | Funder Grant number Engineering and Physical Sciences Research Council EP/L016281/1 |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 18 Mar 2020 14:33 |
Last Modified: | 10 Dec 2021 12:13 |
Status: | Published |
Publisher: | Springer Nature |
Refereed: | Yes |
Identification Number: | 10.1007/s12649-020-00954-1 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:157796 |
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Filename: Robshaw2020_Article_DevelopmentOfACombinedLeaching.pdf
Licence: CC-BY 4.0