Lu, Z., Zhang, H., Lei, W. et al. (2 more authors) (2016) High-Figure-of-Merit Thermoelectric La-Doped A-Site-Deficient SrTiO3 Ceramics. CHEMISTRY OF MATERIALS, 28 (3). pp. 925-935. ISSN 0897-4756
Abstract
ABSTRACT: The structure and thermoelectric (TE) properties of La-doped, A-site-deficient SrTiO3 (Sr1−3x/2LaxTiO3) ceramics sintered in air and N2/5% H2 have been investigated. Airsintered ceramics with 0.10 ≤ x < 0.30 appear cubic by X-ray diffraction (XRD) but exhibit superstructure consistent with a tetragonal cell (a0 a0 c −), according to electron diffraction (ED) studies. 0.30 ≤ x < 0.50 have additional short-range A-site vacancy (VA) ordering, and x ≥ 0.50 are orthorhombic with an a−a−c + tilt system and long-range VA ordering. 0.10 ≤ x ≤ 0.50 reduced in N2/5% H2 are oxygen-deficient and appear cubic in XRD patterns but exhibit superstructure compliant with an a0 a0 c − tilt system by ED. For x = 0.50, additional short-range VA order is observed, and x > 0.50 are orthorhombic with an a−a−c + tilt system and long-range VA ordering. x = 0.15 sintered in N2/5% H2 shows the largest dimensionless TE figure-of-merit ZT = 0.41 at 973 K reported for n-type SrTiO3-based ceramics, suggesting that the accommodation of La through formation of (VSr) coupled with reduction in N2/5% H2 represents a new protocol for the development of oxide-based thermoelectrics.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2016 American Chemical Society. This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited. |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 11 Apr 2016 13:42 |
Last Modified: | 11 Apr 2016 13:45 |
Published Version: | http://dx.doi.org/10.1021/acs.chemmater.5b04616 |
Status: | Published |
Publisher: | American Chemical Society |
Refereed: | Yes |
Identification Number: | 10.1021/acs.chemmater.5b04616 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:97116 |