Zhang, H., Marincel, D.M., Trolier-McKinstry, S. et al. (2 more authors) (2016) Coherent Growth of a-Fe2O3 in Ti and Nd Co-doped BiFeO3 Thin Films. Materials Research Letters, 4 (3). pp. 168-173.
Abstract
Coherent dendritic α-Fe2O3 precipitates were observed to form at the surface of epitaxial films of (Bi0.75Nd0.25)(Fe0.97Ti0.03)O3 (BNFO) grown by pulsed laser deposition. The Fe2O3 dendrites are assemblages of nanosized particles with an approximate length of 500 nm. Through the use of atomic resolution scanning transmission electron microscopy, a transition zone at the BNFO/α- Fe2O3 interface, ∼ 2 unit-cells wide, was observed to be Fe2O3-rich with the perovskite structure. It is proposed that the formation of the Fe2O3-rich perovskite structure encourages epitaxial growth of the α-Fe2O3 rather than the formation of the incoherent Fe2O3 particulate second phase frequently reported in BiFeO3-based thin films.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2016 Informa UK Limited, trading as Taylor & Francis Group. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/Licenses/by/ 4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
Keywords: | Fe2O3 precipitate; BiFeO3 thin film; aberration-corrected scanning transmission electron microscopy; high angle annular dark field imaging |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) |
Funding Information: | Funder Grant number ENGINEERING AND PHYSICAL SCIENCE RESEARCH COUNCIL (EPSRC) EP/I038934/1 |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 07 Mar 2016 11:30 |
Last Modified: | 26 Jun 2017 11:06 |
Published Version: | http://dx.doi.org/10.1080/21663831.2016.1160260 |
Status: | Published |
Publisher: | Taylor & Francis Open |
Refereed: | Yes |
Identification Number: | 10.1080/21663831.2016.1160260 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:96087 |