Nguyen, BN, Adrio, LA, Albrecht, T et al. (5 more authors) (2015) Electronic structures of cyclometalated palladium complexes in the higher oxidation states. Dalton Transactions, 44 (37). pp. 16586-16591. ISSN 1477-9226
Abstract
The electronic and redox properties of a series of cyclometalated Pd complexes with oxidation states of +2, +3 and +4 were examined using a range of currently available spectroscopic and electrochemical techniques. Changes in metal–ligand bond lengths were established by X-ray crystallography and correctly predicted by DFT calculations, from which the frontier orbitals and partial atomic charges can be obtained. X-ray absorption spectroscopy (XAS) revealed interesting XANES features that suggest a synergistic relationship between metal–ligand interactions. The electrochemical study of the Pd(II) dimer was found to contain two sequential oxidative potentials indicative of a weak metal–metal interaction.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © The Royal Society of Chemistry 2015. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Organic Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 04 Oct 2016 15:18 |
Last Modified: | 04 Nov 2016 07:20 |
Published Version: | http://dx.doi.org/10.1039/C5DT02104A |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/C5DT02104A |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:89510 |