Adhitya, K., Alsulami, A., Buckley, A. et al. (2 more authors) (2015) Intensity-Modulated Spectroscopy on Loaded Organic Photovoltaic Cells. IEEE Journal of Photovoltaics, 5 (5). pp. 1414-1421. ISSN 2156-3381
Abstract
We configured a generic digital lock-in amplifier as a light intensity-modulated spectrometer for photovoltaic (PV) cells for intensity-modulated spectroscopy (IMS) up to 250 kHz. We performed IMS on a state-of-the-art bulk heterojunction (BHJ) organic PV (OPV) cell and introduced a new mode of IMS, wherein PV cells work under finite load, including maximum power point (MPP). Quantitative analysis supported by equivalent circuit simulations establishes MPP-IMS as favorable alternative to the commonly used intensity-modulated photovoltage/photocurrent spectroscopy (IMVS/IMPS) modes. Using IMS under finite load, we identify a high-frequency feature that is invisible in both IMPS and IMVS. The feature is ageing-related and becomes more prominent after long-term storage. We propose an extended equivalent circuit model that locates the origin of this feature at the BHJ itself and link it to diffusion of indium ions etched from the transparent electrode by the hole extracting PEDOT:PSS. Finally, we introduce a method to determine BHJ capacitance by IMS without absolute calibration of light intensity.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2015 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other users, including reprinting/ republishing this material for advertising or promotional purposes, creating new collective works for resale or redistribution to servers or lists, or reuse of any copyrighted components of this work in other works. |
Keywords: | Bulk heterojunction (BHJ); intensity-modulated spectroscopy (IMS); maximum power point (MPP); organic photovoltaics(OPV); PEDOT:PSS. |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Physics and Astronomy (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 09 Jun 2015 17:21 |
Last Modified: | 11 Jan 2017 17:17 |
Published Version: | http://dx.doi.org/10.1109/JPHOTOV.2015.2447838 |
Status: | Published |
Publisher: | Institute of Electrical and Electronics Engineers |
Refereed: | Yes |
Identification Number: | 10.1109/JPHOTOV.2015.2447838 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:86779 |