Song, W., Martsinovich, N., Heckl, W.M. et al. (1 more author) (2014) Thermodynamics of halogen bonded monolayer self-assembly at the liquid-solid interface. Chemical Communications, 50 (88). 13465 - 13468. ISSN 1359-7345
Abstract
Monolayer self-assembly of a hexabrominated, three-fold symmetric aromatic molecule is studied at the heptanoic acid-graphite interface. Thermodynamical insights are obtained from an adapted Born-Haber cycle that is utilized to derive the overall enthalpy change including solvent effects. Comparison with theoretical entropy estimates suggests a minor influence of solvation.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2014 Royal Society of Chemistry. This is an author produced version of a paper subsequently published in Chemical Communications. Uploaded in accordance with the publisher's self-archiving policy. |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 31 Oct 2014 14:04 |
Last Modified: | 18 Sep 2015 14:47 |
Published Version: | http://dx.doi.org/10.1039/C4CC06251E |
Status: | Published |
Publisher: | The Royal Society of Chemistry |
Refereed: | Yes |
Identification Number: | 10.1039/C4CC06251E |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:81251 |