Re-Os age constraints and new observations of Proterozoic glacial deposits in the Vazante Group, Brazil

A new Re-Os radiometric age date for an organic-rich shale horizon from the Vazante Group in Brazil, coupled with geological observations, provide evidence for late Mesoproterozoic glacial episodes, conflicting with the general view of greenhouse conditions marked by a eustatic high stand at this time. Field observations of a reverse fault juxtaposing older Mesoproterozoic sedimentary rocks above younger Neoproterozoic strata provide a new stratigraphic framework and reconcile the apparent inversion of U-Pb detrital zircon ages through the succession. Combined, the geochronological, geochemical and stratigraphic evidence suggest that the Vazante Group sediments accumulated along a passive margin of the São Francisco craton and are correlative with the neighboring Paranoá Group. Biomarker, sulfur isotope and iron speciation analyses support the interpretation of a strongly stratified water column during post-glacial transgression and deposition of one of the bituminous shale horizons. The relationship of the glaciogenic Vazante Group to other late Mesoproterozoic successions, such as the non-glacial Atar Group in West Africa and Bylot Supergroup in arctic Canada, however, remains enigmatic.