Stepwise synthesis of a Ru4Cd4 coordination cage using inert and labile subcomponents: introduction of redox activity at specific sites.
Metherell, A.J. and Ward, M.D.
(2014)
Stepwise synthesis of a Ru4Cd4 coordination cage using inert and labile subcomponents: introduction of redox activity at specific sites.
Chemical Communications, 50.
pp. 6330-6332.
Abstract
The kinetically inert mononuclear complex [RuL3](PF6)2 (1 : 3 mixture of fac and mer isomers), with three pendant binding sites, reacts with labile Cd(ii) ions to complete the assembly of a Ru4Cd4 cubic coordination cage in which reversible redox behaviour has been introduced at the Ru(ii) sites.
CORE (COnnecting REpositories)
CORE (COnnecting REpositories)