Chechik, V. (2004) Reduced reactivity of aged Au nanoparticles in ligand exchange reactions. Journal of the American Chemical Society, 126 (25). pp. 7780-7781. ISSN 0002-7863Full text not available from this repository.
Solutions of alkanethiol-protected Au nanoparticles undergo a slow aging process over a period of several days, which dramatically reduces their reactivity in a place-exchange reaction with disulfides. This behavior was tentatively attributed to the reorganization of the most reactive binding sites (e.g., defect sites) on the nanoparticle surface.
|Institution:||The University of York|
|Academic Units:||The University of York > Chemistry (York)|
|Depositing User:||York RAE Import|
|Date Deposited:||08 Apr 2009 11:20|
|Last Modified:||08 Apr 2009 11:20|
|Publisher:||ACS American Chemical Society|