Abbott, L.C., Batchelor, S.N., Oakes, J., Gilbert, B.C., Whitwood, A.C., Lindsay Smith, J.R. and Moore, J.N. (2005) Experimental and computational studies of structure and bonding in parent and reduced forms of the azo dye Orange II. Journal of Physical Chemistry A, 109 (12). pp. 2894-2905. ISSN 1089-5639
The structure and bonding of the azo dye Orange II (Acid Orange 7) in parent and reduced forms have been studied using NMR, infrared, Raman, UV−visible, and electron paramagnetic resonance (EPR) spectroscopy, allied with density functional theory (DFT) calculations on three hydrazone models (no sulfonate, anionic sulfonate, and protonated sulfonate) and one azo model (protonated sulfonate). The calculated structures of the three hydrazone models are similar to each other and that of the model without a sulfonate group (Solvent Yellow 14) closely matches its reported crystal structure. The 1H and 13C NMR resonances of Orange II, assigned directly from 1D and 2D experimental data, indicate that it is present as ≥95% hydrazone in aqueous solution, and as a ca. 70:30 hydrazone:azo mixture in dimethyl sulfoxide at 300 K. Overall, the experimental data from Orange II are matched well by calculations on the hydrazone model with a protonated sulfonate group; the IR, Raman, and UV−visible spectra of Orange II are assigned to specific vibrational modes and electronic transitions calculated for this model. The EPR spectrum obtained on one-electron reduction of Orange II by the 2-hydroxy-2-propyl radical (•CMe2OH) at pH 4 is attributed to the hydrazyl radical produced on protonation of the radical anion. Calculations on reduced forms of the model dyes support this assignment, with electron spin density on the two nitrogen atoms and the naphthyl ring; in addition, they provide estimates of the structures, vibrational spectra, and electronic transitions of the radicals.
|Institution:||The University of York|
|Academic Units:||The University of York > Chemistry (York)|
|Depositing User:||York RAE Import|
|Date Deposited:||17 Apr 2009 12:12|
|Last Modified:||17 Apr 2009 12:12|
|Publisher:||American Chemical Society|