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The vibration-rotation emission spectra of MgH2

Shayesteh, A., Appadoo, D.R.T., Gordon, I. and Bernath, P.F. (2003) The vibration-rotation emission spectra of MgH2. Journal of Chemical Physics, 119 (15). pp. 7785-7788. ISSN 0021-9606

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Abstract

The gaseous MgH2 molecule has been discovered in an electrical discharge inside a high temperature furnace. The vibration–rotation emission spectrum of 24MgH2 was recorded with a Fourier transform spectrometer and the antisymmetric stretching mode (3) was detected near 1589 cm–1. In addition, three hot bands involving 2 and 3 were found and rotationally analyzed. The MgH2 molecule has a linear structure with an R0 Mg–H bond distance of 1.703 327(3) Å.

Item Type: Article
Copyright, Publisher and Additional Information: © 2003 American Institute of Physics.
Institution: The University of York
Academic Units: The University of York > Chemistry (York)
Depositing User: York RAE Import
Date Deposited: 05 Feb 2009 18:40
Last Modified: 05 Feb 2009 18:40
Published Version: http://dx.doi.org/10.1063/1.1609973
Status: Published
Publisher: American Institute of Physics
Identification Number: 10.1063/1.1609973
URI: http://eprints.whiterose.ac.uk/id/eprint/6603

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