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Heterobimetallic lithium alkyltriimido aluminate cages containing the [R'Al(NR)3]4- tetraanion (R' = Bun, Et; R = 2-OMeC6H4)

Copsey, M.C., Jeffery, J.C., Russell, C.A., Slattery, J.M. and Straughan, J.A. (2003) Heterobimetallic lithium alkyltriimido aluminate cages containing the [R'Al(NR)3]4- tetraanion (R' = Bun, Et; R = 2-OMeC6H4). Chemical Communications, 18. pp. 2356-2357. ISSN 1359-7345

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Abstract

Attempted metallation of a triamidoaluminane gives a complex containing the [RAl(NR)3]4– anion whose formal tetranegative charge is the highest charge observed crystallographically for a simple mononuclear imido main group anion system.

Item Type: Article
Institution: The University of York
Academic Units: The University of York > Chemistry (York)
Depositing User: York RAE Import
Date Deposited: 19 Jun 2009 16:20
Last Modified: 19 Jun 2009 16:20
Published Version: http://dx.doi.org/10.1039/b307589c
Status: Published
Publisher: Elsevier
Identification Number: 10.1039/b307589c
URI: http://eprints.whiterose.ac.uk/id/eprint/5883

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