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Synthesis and structure of [Zn(OMe)(L)]-[Zn(OH)(L)].2(BPh4), L = cis,cis-1,3,5-tris[(E,E)-3-(2-furyl) acrylideneamino] cyclohexane: structural models of carbonic anhydrase and liver alcohol dehydrogenase

Cronin, L. and Walton, P.H. (2003) Synthesis and structure of [Zn(OMe)(L)]-[Zn(OH)(L)].2(BPh4), L = cis,cis-1,3,5-tris[(E,E)-3-(2-furyl) acrylideneamino] cyclohexane: structural models of carbonic anhydrase and liver alcohol dehydrogenase. Chemical Communications, 13. pp. 1572-1573. ISSN 1359-7345

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Abstract

Direct reaction of [Zn(OH)(L)]+, L =cis,cis-1,3,5-tris[(E,E)-3-(2-furyl)acrylideneamino]cyclohexane, with methanol gives a mixture of the starting material and [Zn(OMe)(L)]+; structural analysis of the complexes shows that they are models of reactive intermediates in the catalytic cycles of the zinc enzymes carbonic anhydrase and liver alcohol dehydrogenase.

Item Type: Article
Academic Units: The University of York > Chemistry (York)
Depositing User: York RAE Import
Date Deposited: 04 Sep 2009 15:19
Last Modified: 04 Sep 2009 15:19
Published Version: http://dx.doi.org/10.1039/b302895j
Status: Published
Publisher: Elsevier
Identification Number: 10.1039/b302895j
URI: http://eprints.whiterose.ac.uk/id/eprint/5871

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