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The first mu(6)-peroxide transition-metal complex: [Ni(8)(L)(12)(O2](2+)

Brown, E.J., Duhme-Klair, A.K., Elliott, M.I., Thomas-Oates, J.E., Timmins, P.L. and Walton, P.H. (2005) The first mu(6)-peroxide transition-metal complex: [Ni(8)(L)(12)(O2](2+). Angewandte Chemie-International Edition, 44 (9). pp. 1392-1395. ISSN 1433-7851

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Abstract

Caged peroxide: An octanuclear nickel complex, which exhibits peroxide in an unprecedented 6-(1)3 coordination mode, was prepared (see structure: only the Ni8 unit with the central peroxo ligand and the bridging oxygen atoms is shown; green Ni, red O). This mode of binding finally completes the series of symmetrical n-(1)n/2 peroxide binding modes in complexes.

Item Type: Article
Institution: The University of York
Academic Units: The University of York > Chemistry (York)
Depositing User: York RAE Import
Date Deposited: 12 Aug 2009 13:30
Last Modified: 12 Aug 2009 13:30
Published Version: http://dx.doi.org/10.1002/anie.200461892
Status: Published
Publisher: John Wiley & Sons
Identification Number: 10.1002/anie.200461892
URI: http://eprints.whiterose.ac.uk/id/eprint/5568

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