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An [{Fe(mecam)}2]6- bridge in the crystal structure of a ferric enterobactin binding protein

Müller, A., Wilkinson, A.J., Wilson, K.S. and Duhme-Klair, A.-K. (2006) An [{Fe(mecam)}2]6- bridge in the crystal structure of a ferric enterobactin binding protein. Angewandte Chemie-International Edition, 45 (31). pp. 5132-5136. ISSN 1433-7851

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Abstract

Bridging the gap: The dinuclear ferric enterobactin mimic [{Fe(mecam)}2]6- (H6-mecam=1,3,5-N,N,N-tris(2,3-dihydroxybenzoyl)triaminomethylbenzene) is recognized by two periplasmic binding protein molecules (yellow and blue; see structure). The assembly is stabilized through hydrophobic interactions between the ligand backbones of the dinuclear iron complex.

Item Type: Article
Keywords: iron • N,O ligands • proteins • self-assembly • siderophores
Academic Units: The University of York > Chemistry (York)
Depositing User: York RAE Import
Date Deposited: 13 Aug 2009 16:02
Last Modified: 13 Aug 2009 16:02
Published Version: http://dx.doi.org/10.1002/anie.200601198
Status: Published
Publisher: John Wiley & Sons
Identification Number: 10.1002/anie.200601198
URI: http://eprints.whiterose.ac.uk/id/eprint/5560

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