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How to predict the physical properties of ionic liquids: a volume-based approach

Slattery, J.M., Daguenet, C., Dyson, P.J., Schubert, T.J.S. and Krossing, I. (2007) How to predict the physical properties of ionic liquids: a volume-based approach. Angewandte Chemie International, 46 (28). pp. 5384-5388. ISSN 1433-7851

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Abstract

The molecular volume Vm (that is, the sum of the ionic volumes Vion of the constituent ions) of an ionic liquid (IL) in combination with an anion-dependent empirical relationship is all one needs to predict physical properties such as viscosity, conductivity, and density of [N(CN)2]-, [BF4]-, [PF6]-, and [N(SO2CF3)2]- ionic liquids, including those which may as yet only exist on paper.

Item Type: Article
Institution: The University of York
Academic Units: The University of York > Chemistry (York)
Depositing User: York RAE Import
Date Deposited: 13 Aug 2009 16:01
Last Modified: 13 Aug 2009 16:01
Published Version: http://dx.doi.org/10.1002/anie.200700941
Status: Published
Publisher: John Wiley & Sons
Identification Number: 10.1002/anie.200700941
URI: http://eprints.whiterose.ac.uk/id/eprint/5555

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