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High-Activity, Single-Site Mesoporous Pd/Al2O3 Catalysts for Selective Aerobic Oxidation of Allylic Alcohols

Hackett, S.F.J., Brydson, R.M., Gass, M.H., Harvey, I., Newman, A.D., Wilson, K. and Lee, A.F. (2007) High-Activity, Single-Site Mesoporous Pd/Al2O3 Catalysts for Selective Aerobic Oxidation of Allylic Alcohols. Angewandte Chemie International Edition, 46 (45). pp. 8593-8596. ISSN 1433-7851

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Abstract

Pd does it alone: Tailored heterogeneous catalysts offer exciting, alternative, clean technologies for regioselective molecular transformations. A mesoporous alumina support stabilizes atomically dispersed PdII surface sites (see picture, C light gray, O red, Pd dark gray, Al purple, H white), thereby dramatically enhancing catalytic performance in the aerobic selective oxidation of alcohols.

Item Type: Article
Academic Units: The University of York > Chemistry (York)
The University of Leeds > Faculty of Engineering (Leeds) > School of Process, Environmental and Materials Engineering (Leeds) > Institute for Materials Research (Leeds)
Depositing User: York RAE Import
Date Deposited: 21 Aug 2009 10:50
Last Modified: 29 Sep 2010 14:23
Published Version: http://dx.doi.org/10.1002/anie.200702534
Status: Published
Publisher: John Wiley & Sons
Identification Number: 10.1002/anie.200702534
URI: http://eprints.whiterose.ac.uk/id/eprint/5532

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