Fish, C., Green, M., Kilby, R.J., Lynam, J.M., McGrady, J.E., Pantazis, D.A., Russell, C.A., Whitwood, A.C. and Willans, C.E. (2006) A new reaction pathway in organophosphorus chemistry: competing SN2- and AE'-pathways for nucleophilic attack at a phosphorus-cage compound. Angewandte Chemie International Edition, 45 (22). pp. 3628-3631. ISSN 1433-7851
Full text not available from this repository.Abstract
Competition: A combination of 31P NMR spectroscopic and calculational studies have shown that nucleophilic substitution in the phosphorus-carbon cage compound ClP3(CtBu)2 occurs through competing SN2- and AE-type reaction pathways (see scheme for model compound ClP3(CH)2). The AE mechanism results in the formation of a C2v-symmetric intermediate prior to release of the chloride ion.
| Item Type: | Article |
|---|---|
| Academic Units: | The University of York > Chemistry (York) |
| Depositing User: | York RAE Import |
| Date Deposited: | 21 Aug 2009 10:14 |
| Last Modified: | 21 Aug 2009 10:14 |
| Published Version: | http://dx.doi.org/10.1002/anie.200504546 |
| Status: | Published |
| Publisher: | John Wiley & Sons |
| Identification Number: | 10.1002/anie.200504546 |
| URI: | http://eprints.whiterose.ac.uk/id/eprint/5494 |
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