Franken, A., Kilner, C.A. and Kennedy, J.D. (2004) Polyhedral monocarbaborane chemistry. Carboxylic acid derivatives of the [closo-2-CB9H10](-) anion. Chemical Communications, 3. pp. 328-329. ISSN 1359-7345
Abstract
Reaction of B10H14 with para-(OHC)C6H4(COOH) in aqueous KOH gives the [nido-6-CB9H11-6-(C6H4-para-COOH)](-) anion I which upon cluster closure with iodine in alkali solution gives the [closo-2-CB9H9-2-(C6H4-para-COOH)](-) anion 2; an analogous procedure with B10H14 and glyoxalic acid OHCCOOH gives the [closo-2-CB9H9-2-(COOH)](-) anion 4 via the [arachno-6-CB9H13-6-(COOH)](-) anion 3.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © 2008 Royal Society of Chemistry. This is an author produced version of a paper published in Chemical Communications. Uploaded in accordance with the publisher's self archiving policy. |
Dates: |
|
Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) |
Depositing User: | Repository Administrator York |
Date Deposited: | 04 Jun 2008 08:25 |
Last Modified: | 16 Sep 2016 13:36 |
Published Version: | http://dx.doi.org/10.1039/b311853n |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Refereed: | Yes |
Identification Number: | 10.1039/b311853n |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:3932 |