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Macropolyhedral boron-containing cluster chemistry. Cluster assembly about a molybdenum centre. Formation of the 19-vertex [(CO)(2)MoB16H15C2Ph2](-) anion

Carr, M.J., Franken, A. and Kennedy, J.D. (2004) Macropolyhedral boron-containing cluster chemistry. Cluster assembly about a molybdenum centre. Formation of the 19-vertex [(CO)(2)MoB16H15C2Ph2](-) anion. Dalton Transactions, 17. pp. 2612-2613. ISSN 1477-9226

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Abstract

Fusion of nine-vertex [1-Ph-nido-1-CB8H11] with [Mo(CH3CN)3(CO)3] in the presence of tetramethylnaphthalenediamine gives the nineteen-vertex macropolyhedral metallaborane anion [(CO)2MoB16H15C2Ph]− with a molybdenum(VI) twelve-atom coordination sphere.

Item Type: Article
Copyright, Publisher and Additional Information: © 2004 Royal Society of Chemistry. This is an author produced version of a paper published in Dalton Transactions. Uploaded in accordance with the publisher's self archiving policy.
Academic Units: The University of Leeds > Faculty of Maths and Physical Sciences (Leeds) > School of Chemistry (Leeds)
Depositing User: Repository Administrator York
Date Deposited: 22 Apr 2008 17:38
Last Modified: 08 Feb 2013 17:05
Published Version: http://dx.doi.org/10.1039/b410873f
Status: Published
Publisher: Royal Society of Chemistry
Refereed: Yes
Identification Number: 10.1039/b410873f
Related URLs:
URI: http://eprints.whiterose.ac.uk/id/eprint/3751

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