Grigg, R., McCaffrey, S., Sridharan, V., Fishwick, C.W.G., Kilner, C., Korn, S., Bailey, K. and Blacker, J. (2006) Enantioselective synthesis of non-proteinogenic 2-arylallyl-α-amino acids via Pd/In catalytic cascades. Tetrahedron, 62 (52). pp. 12159-12171. ISSN 0040-4020
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Published Version: http://dx.doi.org/10.1016/j.tet.2006.09.098
Abstract
An efficient synthesis of both R- and S-enantiomers of 2-arylallyl-α-amino acids via a diastereoselective Pd/In mediated catalytic allylation of chiral N-sulfinyl-α-imino esters is described. The potential for further enhancement of molecular complexity and creating contiguous chiral centres by interfacing these processes with catalytic cyclisation–anion capture methodology is demonstrated.
| Item Type: | Article |
|---|---|
| Copyright, Publisher and Additional Information: | Copyright © 2006 Elsevier Ltd. This is an author produced version of a paper published in Tetrahedron. |
| Academic Units: | The University of Leeds > Faculty of Maths and Physical Sciences (Leeds) > School of Chemistry (Leeds) |
| Depositing User: | Repository Officer |
| Date Deposited: | 05 Feb 2007 |
| Last Modified: | 08 Feb 2013 17:03 |
| Published Version: | http://dx.doi.org/10.1016/j.tet.2006.09.098 |
| Status: | Published |
| Publisher: | Elsevier |
| Refereed: | Yes |
| Identification Number: | 10.1016/j.tet.2006.09.098 |
| URI: | http://eprints.whiterose.ac.uk/id/eprint/1939 |
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