Alqurashy, B.A., Iraqi, A. orcid.org/0000-0003-3060-6663, Zhang, Y. et al. (1 more author)
(2020)
Pyrene- benzo[1,2,5]thiadiazole based conjugated polymers for application in BHJ solar cells.
Journal of Saudi Chemical Society, 24 (6).
pp. 484-491.
ISSN 1319-6103
Abstract
Ethylhexyloxy-functionalised pyrene (PEH) was prepared and copolymerised with both dithienyl-benzo[c]-[1], [2], [5]thiadiazole and dibithiophenyl-benzo[c]-[1], [2], [5]thiadiazole via a Stille coupling polymerisation method to yield PPEH-DTBT-8 and PPEH-DT2BT-8, respectively. A comparative study was conducted to assess the impact of substituting thiophene for bithiophene repeat units upon the resulting properties of the conjugated polymers. PPEH-DT2BT-8 which has bithiophene spacers between pyrene and benzothiadiazole repeat units, exhibited a narrower optical and electrochemical band gap relative to PPEH-DTBT-8; a consequence of the incorporating bithiophene spacer units which promote intramolecular charge transfer between the electron donating and electron accepting moieties. Both PPEH-DTBT-8 and PPEH-DT2BT-8 showed deep HOMO levels of -5.54 and -5.50 eV, respectively. The polymers possess good thermal stabilities with degradation temperatures in excess of 310 °C. The photovoltaic performance of the two polymers was studied by fabricating bulk heterojunction (BHJ) photovoltaic devices using PC70BM as the acceptor. PPEH-DTBT-8 and PPEH-DT2BT-8 demonstrated efficiencies of 0.33 and 1.83%, respectively. The higher efficiency of PPEH-DT2BT-8 can be attributed to vastly improved FF and Jsc values.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2020 The Authors. Under a Creative Commons license (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
Keywords: | Benzothiadiazole; Conjugated polymers; Photovoltaic; BHJ |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) The University of Sheffield > Faculty of Science (Sheffield) > Department of Physics and Astronomy (Sheffield) |
Funding Information: | Funder Grant number ENGINEERING AND PHYSICAL SCIENCE RESEARCH COUNCIL EP/J017361/1 ENGINEERING AND PHYSICAL SCIENCE RESEARCH COUNCIL EP/M014797/1 |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 04 May 2020 08:19 |
Last Modified: | 17 Sep 2021 13:14 |
Status: | Published |
Publisher: | Elsevier BV |
Refereed: | Yes |
Identification Number: | 10.1016/j.jscs.2020.04.004 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:160057 |
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