A low cost, rapid impedance measurement technique suitable for Li-ion health diagnosis in battery energy storage systems

Battery energy storage is becoming a vital part of green energy systems. Prediction of the state of health of energy storage systems is difficult as it relies on a number of parameters. Pseudo Random Binary Sequence (PRBS) excitation of energy storage batteries has been shown to be a valid method of battery parameter identification for lead acid batteries [1]. The purpose of this work is to validate PRBS test data from a 3Ah LiFePO4 cell forming part of an EV battery-pack cell against Electrochemical Impedance Spectroscopy (EIS) data obtained from an industry-standard potentiostat (Solartron 1480). PRBS results are obtained in under 200 seconds on easily reproducible equipment which can be built into a green energy battery management system, while the EIS process takes over two hours on prohibitively expensive laboratory equipment. This work validates PRBS as a fast and portable method of obtaining the impedance spectrum of Lithium Ion cells, which can then be used to obtain information about SoH of the BESS.