Molecular-salt hybrids; integration of ammonia borane into lithium halides
Cascallana-Matías, I., Breternitz, J., Baker, A. et al. (3 more authors)
(2019)
Molecular-salt hybrids; integration of ammonia borane into lithium halides.
Inorganic Chemistry Frontiers, 6 (3).
pp. 808-812.
ISSN 2052-1545
Abstract
New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I−, BH4−; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.
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