Lawrenson, Stefan B., Hart, Sam, Ingram, Ian D.V. et al. (3 more authors) (2018) Ring-Opening Metathesis Polymerization of Tertiary Amide Monomers Derived from a Biobased Oxanorbornene. ACS Sustainable Chemistry and Engineering. pp. 9744-9752. ISSN 2168-0485
Abstract
Ring-opening metathesis polymerization (ROMP) of biobased oxanorbornene amides by Grubbs second generation catalyst was used to prepare a range of well-defined homo- and copolymers. A series of 11 amide monomers, featuring a variety of functionalities including amino acids and peptides, have been synthesized from a biobased oxanorbornene acid, prepared through the 100% atom economical tandem Diels-Alder lactonization between itaconic anhydride and furfuryl alcohol. The polymerization has been shown to be well-controlled, with the prepared homo- and copolymers possessing controlled molecular weights with narrow polydispersities.
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2018 American Chemical Society. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details. |
Keywords: | Diels-Alder, Furfuryl alcohol, Itaconic anhydride, Lactonization, Platform molecules, Ring-opening metathesis polymerization |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 18 Sep 2018 14:00 |
Last Modified: | 06 Dec 2023 12:39 |
Published Version: | https://doi.org/10.1021/acssuschemeng.8b00779 |
Status: | Published |
Refereed: | Yes |
Identification Number: | https://doi.org/10.1021/acssuschemeng.8b00779 |
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