White, T.W., Martsinovich, N. orcid.org/0000-0001-9226-8175, Troisi, A. et al. (1 more author) (2018) Quantifying the 'subtle interplay' between intermolecular and molecule-substrate interactions in molecular assembly on surfaces. Journal of Physical Chemistry C, 122 (31). pp. 17954-17962. ISSN 1932-7447
Abstract
The effect of the concurrent action of intermolecular and molecule-substrate interactions on the two-dimensional (2-D) self-assembly of organic molecules on solid surfaces is investigated in a combined experimental and theoretical effort. Scanning tunnelling microscopy measurements of terephthalic acid on the Cu(111) surface, a model system where the interplay between the two interactions is particularly evident, are used to develop a general, simple and computationally inexpensive model that quantitatively accounts for the experimental observations. The model, related to the well-known Frenkel-Kontorova model, offers a comprehensive description of the 'subtle interplay' between intermolecular and molecule-substrate interactions and provides a qualitative and quantitative predictive capability in the design and fabrication of 2-D molecular nanostructures at surfaces.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2018 American Chemical Society. This publication is licensed under CC-BY (https://creativecommons.org/licenses/by/4.0/). |
Keywords: | Adsorption; Molecular interactions; Molecular structure; Supramolecular chemistry; Supramolecular structures and assemblies |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 09 Aug 2018 14:16 |
Last Modified: | 18 Apr 2024 13:25 |
Status: | Published |
Publisher: | American Chemical Society |
Refereed: | Yes |
Identification Number: | 10.1021/acs.jpcc.8b06797 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:134366 |