Riss, B., Garreau, M., Fricero, P. et al. (3 more authors) (2017) Total synthesis of TMS-ent-bisabolangelone. Tetrahedron, 73 (23). pp. 3202-3212. ISSN 0040-4020
Abstract
The absolute configuration of bisabolangelone has been established by an eleven step total synthesis of the corresponding TMS protected antipode starting from (R)-(+)-pulegone. Comparison of the TMS-derivatives by GC on a chiral column, allowed us to assign the absolute configuration of the synthetic compound and thus of the corresponding natural product. The latter has been confirmed by the Mosher's ester analysis of the known secondary carbinol derivative.
Metadata
| Authors/Creators: |
|
|---|---|
| Copyright, Publisher and Additional Information: | © 2017 Elsevier. |
| Dates: |
|
| Institution: | The University of Sheffield |
| Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
| Depositing User: | Symplectic Sheffield |
| Date Deposited: | 08 Jun 2017 08:43 |
| Last Modified: | 08 Jun 2017 08:43 |
| Published Version: | https://doi.org/10.1016/j.tet.2017.04.042 |
| Status: | Published |
| Publisher: | Elsevier |
| Refereed: | Yes |
| Identification Number: | https://doi.org/10.1016/j.tet.2017.04.042 |
Download not available
A full text copy of this item is not currently available from White Rose Research Online
CORE (COnnecting REpositories)
CORE (COnnecting REpositories)