Ismail, M.S., Ingham, D.B., Ma, L. et al. (2 more authors) (2017) Effects of catalyst agglomerate shape in polymer electrolyte fuel cells investigated by a multi-scale modelling framework. Energy, 122. pp. 420-430. ISSN 0360-5442
Abstract
A multi-scale modelling framework is developed for the PEFC cathode electrode. Unlike the conventional agglomerate model, the effects of the microstructure of the agglomerate are numerically coupled to the fuel cell-scale model in this framework. This is performed through solving the agglomerate-scale model first and subsequently extracting and using the data required to generate the performance curves in the fuel cell-scale model. This enables one to freely investigate the structure of the agglomerate without being limited to the only three agglomerate shapes that can be investigated using the conventional agglomerate model: spheres, long cylinders with sealed ends and long slabs with sealed ends. The numerical studies conducted in this work using the developed framework have revealed that the performance of the cathode electrode is highly sensitive to the specific surface area of the agglomerate if the size of the latter is relatively large, i.e. of the order of 1000 nm. Namely, the maximum reported current density has increased by about 60% when changing from the ‘large’ spherical agglomerate to the ‘large’ cylindrical agglomerate. Also, it has been shown that a slight change in the structure of the agglomerate may significantly improve the fuel cell performance.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2017 Elsevier Ltd. This is an author produced version of a paper subsequently published in Energy. Uploaded in accordance with the publisher's self-archiving policy. Article available under the terms of the CC-BY-NC-ND licence (https://creativecommons.org/licenses/by-nc-nd/4.0/) |
Keywords: | PEFCs; Agglomerate model; Multi-scale model; Numerical coupling |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Mechanical Engineering (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 03 Feb 2017 12:57 |
Last Modified: | 23 Jan 2018 01:38 |
Published Version: | https://doi.org/10.1016/j.energy.2017.01.092 |
Status: | Published |
Publisher: | Elsevier |
Refereed: | Yes |
Identification Number: | 10.1016/j.energy.2017.01.092 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:111443 |