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Creation of dense polymer brush layers by the controlled deposition of an amphiphilic responsive comb polymer

Tomlinson, M.R., Cousin, F. and Geoghegan, M. (2009) Creation of dense polymer brush layers by the controlled deposition of an amphiphilic responsive comb polymer. Polymer, 50 (20). pp. 4829-4836. ISSN 0032-3861

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We introduce a copolymer with a comb topology that has been engineered to assemble in a brush configuration at an air-water interface. The molecule comprises a 6.1 kDa poly(methyl methacrylate) backbone with a statistical amount of poly[2-(dimethyl amino)ethyl methacrylate] polybase side chains averaging 2.43 per backbone.. Brush layers deposited with the hydrophobic PMMA backbone adsorbed to hydrophobized silicon are stable in water even when stored at pH values less than 2.0 for over 24 h. The use of a Langmuir trough allows a simple controlled deposition of the layers at a variety of grafting densities. Depth profiling of brush layers was performed using neutron reflectometry and reveals a significant shifting of the responsiveness of the layer upon changing the grafting density. The degree of swelling of the layers at a pH value of 4 (below the pK(b)) decreases as grafting density increases. Lowering the pH of the subphase during deposition causes the side chains to become charged and more hydrophilic extending to a brush-like configuration while at neutral pH the side chains lie in a "pancake" conformation at the interface. (C) 2009 Elsevier Ltd. All rights reserved.

Item Type: Article
Copyright, Publisher and Additional Information: © 2009 Elsevier. This is an author produced version of a paper subsequently published in Polymer. Uploaded in accordance with the publisher's self-archiving policy.
Keywords: Transfer Radical Polymerization; Air-Water-Interface; Molecular-Weight Distribution; Diblock Copolymer Monolayers; Atomic-Force Microscopy; Air/Water Interface; Block-Copolymers; Star Polymer; Surface; Chain
Institution: The University of Sheffield
Academic Units: The University of Sheffield > Faculty of Science (Sheffield) > Department of Physics and Astronomy (Sheffield)
Depositing User: Miss Anthea Tucker
Date Deposited: 18 Jan 2010 09:22
Last Modified: 08 Feb 2013 16:59
Published Version: http://dx.doi.org/10.1016/j.polymer.2009.05.021
Status: Published
Publisher: Elsevier
Refereed: Yes
Identification Number: 10.1016/j.polymer.2009.05.021
URI: http://eprints.whiterose.ac.uk/id/eprint/10274

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