Alghamdi, A. A. B., Imragaa, A., Abdel-Halim, E. S. et al. (1 more author) (2016) Synthesis and characterization of novel thiophene and carbazole-based polymers - optical and electrochemical characterization. International Journal of Electrochemical Science, 11 (6). pp. 5111-5127. ISSN 1452-3981
Abstract
A donor/acceptor series of carbazole copolymers, composed of alternating 2,7-linked 3,6-difluoro-9-(1-octyl-nonyl)-carbazole units and bithiophene repeated units [P1], 5,7-bis(5-bromothiophen-2-yl)-2,3-bis(4-(2-ethylhexyloxy) phenyl) thieno[3,4-b]pyrazine repeated units [P2] and bithiophene mixed with 5,7-bis(5-bromothiophen-2-yl)-2,3-bis(4-(2-ethylhexyloxy) phenyl) thieno[3,4-b]pyrazine repeated units [P3] have been prepared following Suzuki polymerisation procedures. The route of synthesis and characterisation techniques of this novel class of materials, together with their photo-physical and electrochemical properties are presented in this study. The polymers were characterised by 1H NMR, 13C NMR and Elemental Analysis. Molecular weights were estimated using gel permeation chromatography (GPC). The thermal stability behaviour for polymers was investigated using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The electronic and photo-physical properties were investigated by use of cyclic voltammetry (CV) and UV-Vis spectroscopy, respectively.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2016 The Authors. Published by ESG (www.electrochemsci.org). This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecom mons.org/licenses/by/4.0/). |
Keywords: | Organic solar cell; Conjugated polymer; Band gap |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 19 Jul 2016 13:40 |
Last Modified: | 19 Jul 2016 13:40 |
Published Version: | http://dx.doi.org/10.20964/2016.06.57 |
Status: | Published |
Publisher: | ESG |
Refereed: | Yes |
Identification Number: | 10.20964/2016.06.57 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:101499 |