McEllin, Alice Jane, Goult, Christopher A., Whitwood, Adrian C. et al. (2 more authors) (2023) On the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand. Dalton Transactions. D2DT04114F. pp. 872-876. ISSN 1477-9226
Abstract
The C^N^C ligand 2,6-bis(2,3-dialkoxyphenyl)pyridine forms dimercury and orthopalladated complexes, both of which may be transmetallated to gold(iii) complexes; the gold complexes may also be formed directly in a Rh(iii)-catalysed process, hence it is possible to circumvent the use of organomercury intermediates in the synthesis of this important class of compound.
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Item Type: | Article | ||||
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Copyright, Publisher and Additional Information: | Funding Information: We thank the University of York for funding (AJM & CAG). JML is supported by a Royal Society Industry Fellowship. Publisher Copyright: © 2023 The Royal Society of Chemistry. | ||||
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Institution: | The University of York | ||||
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) | ||||
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Depositing User: | Pure (York) | ||||
Date Deposited: | 31 Jan 2023 15:20 | ||||
Last Modified: | 10 Mar 2024 00:13 | ||||
Published Version: | https://doi.org/10.1039/d2dt04114f | ||||
Status: | Published | ||||
Refereed: | Yes | ||||
Identification Number: | https://doi.org/10.1039/d2dt04114f | ||||
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