Effect of cyclic freezing and thawing on the microstructure of composite cements

Mixed performance of composite cements exposed to freeze-thaw has been reported. A detailed understanding of the degradation mechanism is also lacking. This study investigates the microstructure of composite slag cements with and without limestone subjected to cyclic freezing and thawing. Freeze-thaw was assessed on concrete samples in accordance with CEN/TR 15177 but with a modified temperature profile. Microstructure was characterized by SEM and thermogravimetric analysis. The results indicate decalcification through carbonation and then leaching as dominant degradation mechanisms. This has implications on the pore structure and hence the water suction capacity and progression of the ice-front in concrete.