Gilbert, B.C., Lindsay Smith, J.R., Mairata i Payeras, A. et al. (1 more author) (2004) Formation and reaction of O=MnV species in the oxidation of phenolic substrates with H2O2 catalysed by the dinuclear manganese(IV) 1,4,7-trimethyl-1,4,7-triazacyclononane complex [MnIVV2(µ-O)3(TMTACN)2](PF6)2. Organic and Biomolecular Chemistry, 2 (2). pp. 1176-1180. ISSN 1477-0520
Abstract
The oxidation of phenolic substrates with H2O2 catalysed by [MnIV2(µ-O)3(TMTACN)2](PF6)2 1,(TMTACN, 1,4,7-trimethyl-1,4,7-triazacyclononane) has been investigated by use of ESI mass spectrometry. The role of the phenols as one-electron reductants and as co-ligands in the stabilisation and reaction of an intermediate OMnV species has been analysed and the presence of a variety of manganese species in solution has been explained. Our results lead to a proposed mechanism for the catalytic oxidation of phenols in this system.
Graphical abstract image for this article (ID: b315427k)
Metadata
| Authors/Creators: |
|
|---|---|
| Dates: |
|
| Institution: | The University of York |
| Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
| Depositing User: | York RAE Import |
| Date Deposited: | 09 Feb 2009 11:47 |
| Last Modified: | 09 Feb 2009 11:47 |
| Published Version: | http://dx.doi.org/10.1039/b315427k |
| Status: | Published |
| Publisher: | Royal Society Chemistry |
| Identification Number: | https://doi.org/10.1039/b315427k |
CORE (COnnecting REpositories)
CORE (COnnecting REpositories)