Inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions of 4-silylated oxazoles

Ducept, P.C. and Marsden, S.P. (2002) Inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions of 4-silylated oxazoles. Arkivoc, 2002 (6). pp. 22-34. ISSN 1424-6376

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Abstract

4-Silylated oxazoles have been shown to undergo inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions with electron-poor alkynes to generate polysubstituted furans. The ease of synthesis of the requisite oxazoles by the rhodium-catalysed condensation of nitriles with silylated diazoacetate greatly increases the scope of this reaction.

Item Type:	Article
Copyright, Publisher and Additional Information:	© 2002 ARKAT
Keywords:	silylated oxazoles, diazoacetate, furans, Diels-Alder, retro-Diels-Alder
Academic Units:	The University of Leeds > Faculty of Maths and Physical Sciences (Leeds) > School of Chemistry (Leeds)
Depositing User:	Repository Officer
Date Deposited:	10 Jan 2006
Last Modified:	08 Feb 2013 17:02
Published Version:	http://www.arkat-usa.org/ark/journal/2002/I06_Rees...
Status:	Published
Refereed:	Yes
URI:	http://eprints.whiterose.ac.uk/id/eprint/925

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