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Inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions of 4-silylated oxazoles

Ducept, P.C. and Marsden, S.P. (2002) Inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions of 4-silylated oxazoles. Arkivoc, 2002 (6). pp. 22-34. ISSN 1424-6376

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4-Silylated oxazoles have been shown to undergo inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions with electron-poor alkynes to generate polysubstituted furans. The ease of synthesis of the requisite oxazoles by the rhodium-catalysed condensation of nitriles with silylated diazoacetate greatly increases the scope of this reaction.

Item Type: Article
Copyright, Publisher and Additional Information: © 2002 ARKAT
Keywords: silylated oxazoles, diazoacetate, furans, Diels-Alder, retro-Diels-Alder
Institution: The University of Leeds
Academic Units: The University of Leeds > Faculty of Maths and Physical Sciences (Leeds) > School of Chemistry (Leeds)
Depositing User: Repository Officer
Date Deposited: 10 Jan 2006
Last Modified: 07 Jun 2014 03:13
Published Version: http://www.arkat-usa.org/ark/journal/2002/I06_Rees...
Status: Published
Refereed: Yes
URI: http://eprints.whiterose.ac.uk/id/eprint/925

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