Ducept, P.C. and Marsden, S.P. (2002) Inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions of 4-silylated oxazoles. Arkivoc, 2002 (6). pp. 22-34. ISSN 1424-6376Full text available as:
Available under licence : See the attached licence file.
4-Silylated oxazoles have been shown to undergo inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions with electron-poor alkynes to generate polysubstituted furans. The ease of synthesis of the requisite oxazoles by the rhodium-catalysed condensation of nitriles with silylated diazoacetate greatly increases the scope of this reaction.
|Copyright, Publisher and Additional Information:||© 2002 ARKAT|
|Keywords:||silylated oxazoles, diazoacetate, furans, Diels-Alder, retro-Diels-Alder|
|Institution:||The University of Leeds|
|Academic Units:||The University of Leeds > Faculty of Maths and Physical Sciences (Leeds) > School of Chemistry (Leeds)|
|Depositing User:||Repository Officer|
|Date Deposited:||10 Jan 2006|
|Last Modified:||07 Jun 2014 03:13|
Actions (login required)