Doyle, CM, Cunniffe, JP, Krasnikov, SA et al. (5 more authors) (2014) Ni-Cu ion exchange observed for Ni(II)-porphyrins on Cu(111). Chemical Communications, 50. 3447 - 3449. ISSN 1359-7345
Abstract
A Ni-Cu ion exchange has been observed for (5,15-dibromo-10,20-diphenylporphyrinato)nickel(II) (NiDBrDPP) and (5,10,15,20-tetrakis(4-bromophenyl)porphyrinato)nickel(II) (NiTBrPP) on Cu(111). The ion exchange proceeds at a faster rate for the NiDBrDPP/Cu(111) system compared to NiTBrPP/Cu(111). This is explained in terms of the macrocycle-substrate distance and the distortions that occur when the molecules are deposited on the Cu(111) surface.
Metadata
| Authors/Creators: |
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| Keywords: | Copper; Kinetics; Nickel; Porphyrins; Spectrum Analysis |
| Dates: |
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| Institution: | The University of Leeds |
| Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Colour Science (Leeds) |
| Depositing User: | Symplectic Publications |
| Date Deposited: | 09 Oct 2015 12:39 |
| Last Modified: | 04 Dec 2015 20:42 |
| Published Version: | http://dx.doi.org/10.1039/c3cc48913b |
| Status: | Published |
| Publisher: | Royal Society of Chemistry |
| Identification Number: | https://doi.org/10.1039/c3cc48913b |
| Related URLs: |
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