Gilbert, B.C., Lindsay Smith, J.R., Mairata i Payeras, A. and Oakes, J. (2004) Formation and reaction of O=MnV species in the oxidation of phenolic substrates with H2O2 catalysed by the dinuclear manganese(IV) 1,4,7-trimethyl-1,4,7-triazacyclononane complex [MnIVV2(µ-O)3(TMTACN)2](PF6)2. Organic and Biomolecular Chemistry, 2 (2). pp. 1176-1180. ISSN 1477-0520Full text not available from this repository.
The oxidation of phenolic substrates with H2O2 catalysed by [MnIV2(µ-O)3(TMTACN)2](PF6)2 1,(TMTACN, 1,4,7-trimethyl-1,4,7-triazacyclononane) has been investigated by use of ESI mass spectrometry. The role of the phenols as one-electron reductants and as co-ligands in the stabilisation and reaction of an intermediate OMnV species has been analysed and the presence of a variety of manganese species in solution has been explained. Our results lead to a proposed mechanism for the catalytic oxidation of phenols in this system.
Graphical abstract image for this article (ID: b315427k)
|Academic Units:||The University of York > Chemistry (York)|
|Depositing User:||York RAE Import|
|Date Deposited:||09 Feb 2009 11:47|
|Last Modified:||09 Feb 2009 11:47|
|Publisher:||Royal Society Chemistry|
Actions (login required)