Cockett, C.R. and Watkins, M.J. (2004) Hydrogenic Rydberg states of molecular van der Waals complexes: Resolved Rydberg spectroscopy of DABCO-N2. Physical Review Letters, 92 (4). 043001-1. ISSN 0031-9007
The complementary threshold ionization techniques of MATI and ZEKE spectroscopy have been used to reveal well-resolved, long-lived (>10 μs) hydrogenic Rydberg series (50≤n≤98) in a van der Waals complex formed between a polyatomic molecule and a diatomic molecule for the first time. The series are observed within 50 cm-1 of the adiabatic ionization threshold as well as two core-excited thresholds corresponding to excitation of up to two quanta in the van der Waals vibrational mode.
|Institution:||The University of York|
|Academic Units:||The University of York > Chemistry (York)|
|Depositing User:||York RAE Import|
|Date Deposited:||23 Feb 2009 14:48|
|Last Modified:||23 Feb 2009 14:48|
|Publisher:||American Physical Society|