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Hydrogenic Rydberg states of molecular van der Waals complexes: Resolved Rydberg spectroscopy of DABCO-N2

Cockett, C.R. and Watkins, M.J. (2004) Hydrogenic Rydberg states of molecular van der Waals complexes: Resolved Rydberg spectroscopy of DABCO-N2. Physical Review Letters, 92 (4). 043001-1. ISSN 0031-9007

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Abstract

The complementary threshold ionization techniques of MATI and ZEKE spectroscopy have been used to reveal well-resolved, long-lived (>10   μs) hydrogenic Rydberg series (50≤n≤98) in a van der Waals complex formed between a polyatomic molecule and a diatomic molecule for the first time. The series are observed within 50  cm-1 of the adiabatic ionization threshold as well as two core-excited thresholds corresponding to excitation of up to two quanta in the van der Waals vibrational mode.

Item Type: Article
Institution: The University of York
Academic Units: The University of York > Chemistry (York)
Depositing User: York RAE Import
Date Deposited: 23 Feb 2009 14:48
Last Modified: 23 Feb 2009 14:48
Published Version: http://dx.doi.org/10.1103/PhysRevLett.92.043001
Status: Published
Publisher: American Physical Society
Identification Number: 10.1103/PhysRevLett.92.043001
URI: http://eprints.whiterose.ac.uk/id/eprint/7259

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