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Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction.

Bonnet, L.G. and Douthwaite, R.E. (2003) Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction. Organometallics, 22 (21). pp. 4187-4189. ISSN 0276-7333

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Abstract

Silver(I) and palladium(II) complexes of new chiral N-heterocyclic carbene (NHC)−imine ligands derived from trans-1,2-diaminocyclohexane have been prepared. These ligands have been applied to a palladium(II)-catalyzed asymmetric allylic alkylation reaction giving a maximum ee of 92%.

Item Type: Article
Academic Units: The University of York > Chemistry (York)
Depositing User: York RAE Import
Date Deposited: 12 Mar 2009 11:24
Last Modified: 12 Mar 2009 11:24
Published Version: http://dx.doi.org/10.1021/om034050z
Status: Published
Publisher: Johns Hopkins University Press
Identification Number: 10.1021/om034050z
URI: http://eprints.whiterose.ac.uk/id/eprint/7135

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