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Catalytic asymmetric synthesis of ferrocenes and P-stereogenic bisphosphines

Genet, C., Canipa, S.J., O'Brien, P. and Taylor, S. (2006) Catalytic asymmetric synthesis of ferrocenes and P-stereogenic bisphosphines. Journal Of The American Chemical Society, 128 (39). pp. 9336-9337. ISSN 0002-7863

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Abstract

The catalytic asymmetric synthesis of planar chiral ferrocenes and P-stereogenic phosphines and bisphosphines (important classes of chiral ligands for metal-catalyzed asymmetric processes) is successfully demonstrated using n-BuLi or s-BuLi in combination with substoichiometric quantities (0.1−0.5 equiv) of (−)-sparteine or the (+)-sparteine surrogate.

Item Type: Article
Academic Units: The University of York > Chemistry (York)
Depositing User: York RAE Import
Date Deposited: 03 Apr 2009 15:16
Last Modified: 03 Apr 2009 15:16
Published Version: http://dx.doi.org/10.1021/ja062616f
Status: Published
Publisher: ACS American Chemical Society
Identification Number: 10.1021/ja062616f
URI: http://eprints.whiterose.ac.uk/id/eprint/6887

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