Genet, C., Canipa, S.J., O'Brien, P. and Taylor, S. (2006) Catalytic asymmetric synthesis of ferrocenes and P-stereogenic bisphosphines. Journal Of The American Chemical Society, 128 (39). pp. 9336-9337. ISSN 0002-7863
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Published Version: http://dx.doi.org/10.1021/ja062616f
Abstract
The catalytic asymmetric synthesis of planar chiral ferrocenes and P-stereogenic phosphines and bisphosphines (important classes of chiral ligands for metal-catalyzed asymmetric processes) is successfully demonstrated using n-BuLi or s-BuLi in combination with substoichiometric quantities (0.1−0.5 equiv) of (−)-sparteine or the (+)-sparteine surrogate.
| Item Type: | Article |
|---|---|
| Academic Units: | The University of York > Chemistry (York) |
| Depositing User: | York RAE Import |
| Date Deposited: | 03 Apr 2009 15:16 |
| Last Modified: | 03 Apr 2009 15:16 |
| Published Version: | http://dx.doi.org/10.1021/ja062616f |
| Status: | Published |
| Publisher: | ACS American Chemical Society |
| Identification Number: | 10.1021/ja062616f |
| URI: | http://eprints.whiterose.ac.uk/id/eprint/6887 |
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