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Metallaborane reaction chemistry. A facile and reversible dioxygen capture by a B-frame-supported bimetallic: structure of [(PMe2Ph)(4)(O-2)Pt2B10H10]

Bould, J., McInnes, Y.M., Carr, M.J. and Kennedy, J.D. (2004) Metallaborane reaction chemistry. A facile and reversible dioxygen capture by a B-frame-supported bimetallic: structure of [(PMe2Ph)(4)(O-2)Pt2B10H10]. ChemicalL Communications (21). pp. 2380-2381. ISSN 1359-7345

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Abstract

[(PMe2Ph)(4)Pt2B10H10] 1 reversibly takes up atmospheric dioxygen to give the fluxional dioxygen-dimetallaborane complex [(PMe2Ph)(4)(O-2)Pt2B10H10] 2, which has Pt-Pt 2.7143(3), Pt-O 2.141(4) and 2.151(4) and O-O 1.434(6) Angstrom.

Item Type: Article
Copyright, Publisher and Additional Information: © 2008 Royal Society of Chemistry. This is an author produced version of a paper published in Chemical Communications. Uploaded in accordance with the publisher's self archiving policy.
Keywords: Dimetallaboranes; Metallaborane reaction chemistry; Cluster bridging ligands; Dioxygen-diplatinum complex, Borane clusters; NMR; X-ray diffraction analysis; Diplatinum complex of molecular dioxygen; Dioxygen, reversible uptake by a dimetal system
Institution: The University of Leeds
Academic Units: The University of Leeds > Faculty of Maths and Physical Sciences (Leeds) > School of Chemistry (Leeds)
Depositing User: Repository Administrator York
Date Deposited: 04 Jun 2008 08:27
Last Modified: 08 Feb 2013 17:05
Published Version: http://dx.doi.org/10.1039/b406974a
Status: Published
Publisher: Royal Society of Chemistry
Refereed: Yes
Identification Number: 10.1039/b406974a
Related URLs:
URI: http://eprints.whiterose.ac.uk/id/eprint/3935

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