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Polyhedral monocarbaborane chemistry. Carboxylic acid derivatives of the [closo-2-CB9H10](-) anion

Franken, A., Kilner, C.A. and Kennedy, J.D. (2004) Polyhedral monocarbaborane chemistry. Carboxylic acid derivatives of the [closo-2-CB9H10](-) anion. Chemical Communications, 3. pp. 328-329. ISSN 1359-7345

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Abstract

Reaction of B10H14 with para-(OHC)C6H4(COOH) in aqueous KOH gives the [nido-6-CB9H11-6-(C6H4-para-COOH)](-) anion I which upon cluster closure with iodine in alkali solution gives the [closo-2-CB9H9-2-(C6H4-para-COOH)](-) anion 2; an analogous procedure with B10H14 and glyoxalic acid OHCCOOH gives the [closo-2-CB9H9-2-(COOH)](-) anion 4 via the [arachno-6-CB9H13-6-(COOH)](-) anion 3.

Item Type: Article
Copyright, Publisher and Additional Information: © 2008 Royal Society of Chemistry. This is an author produced version of a paper published in Chemical Communications. Uploaded in accordance with the publisher's self archiving policy.
Institution: The University of Leeds
Academic Units: The University of Leeds > Faculty of Maths and Physical Sciences (Leeds) > School of Chemistry (Leeds)
Depositing User: Repository Administrator York
Date Deposited: 04 Jun 2008 08:25
Last Modified: 08 Feb 2013 17:05
Published Version: http://dx.doi.org/10.1039/b311853n
Status: Published
Publisher: Royal Society of Chemistry
Refereed: Yes
Identification Number: 10.1039/b311853n
URI: http://eprints.whiterose.ac.uk/id/eprint/3932

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