Dennis, F., Robertson, C. and Partridge, B. orcid.org/0000-0002-8550-9994 (2020) Nickel-catalysed allylboration of aldehydes. SYNTHESIS, 52 (13). pp. 1903-1914. ISSN 0039-7881
Abstract
A nickel catalyst for the allylboration of aldehydes is reported, facilitating the preparation of homoallylic alcohols in high diastereoselectivity. The observed diastereoselectivities and NMR experiments suggest that allylation occurs through a well-defined six-membered transition state, with nickel acting as a Lewis acid.
Metadata
Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2020 Georg Thieme Verlag Stuttgart. This is an author-produced version of a paper subsequently published in SYNTHESIS. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | allylboration; boronic esters; catalysis; homoallylic alcohols; nickel |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 09 Jul 2020 12:57 |
Last Modified: | 18 Mar 2021 01:38 |
Status: | Published online |
Publisher: | Thieme Publishing |
Refereed: | Yes |
Identification Number: | https://doi.org/10.1055/s-0039-1690091 |