Bukvic, Alexander J, Crivoi, Dana Georgiana, Garwood, Hollie G et al. (4 more authors) (2020) Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation : SMOM@polymer. Chemical communications. D0CC01140A. ISSN 1364-548X
Abstract
Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(Cy2PCH2CH2PCy2)(NBA)][BArF4]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.
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Copyright, Publisher and Additional Information: | This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details. | ||||||
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Institution: | The University of York | ||||||
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) | ||||||
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Depositing User: | Pure (York) | ||||||
Date Deposited: | 06 Mar 2020 10:20 | ||||||
Last Modified: | 06 Dec 2023 13:35 | ||||||
Published Version: | https://doi.org/10.1039/d0cc01140a | ||||||
Status: | Published online | ||||||
Refereed: | Yes | ||||||
Identification Number: | https://doi.org/10.1039/d0cc01140a |