Pepper, S.E., Whitte, K.R., Harwood, L.M. et al. (3 more authors) (2017) Cobalt and nickel uptake by silica-based extractants. Separation Science and Technology. ISSN 0149-6395
Abstract
The pKas of ethyl/butyl phosphonate silica (EBP-Si) have been determined, and the removal of cobalt and nickel from solution was investigated as a function of various parameters and compared with those of Purolite S950. pH uptake experiments suggested a combination of ion exchange and acid dissociation of the surface occurring. Isotherm data, fitted using the Langmuir and Dubinin–Radushkevich (D-R) models, indicated that stronger complexes formed with S950 than with EBP-Si. Kinetic data, fitted using a pseudo-second-order model, suggested that the rate-determining process is the reaction of metal ions with the chelating functionality of the resin. Uptake by EBP-Si is two to three times faster than that on S950.
Metadata
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Copyright, Publisher and Additional Information: | This is an Accepted Manuscript of an article published by Taylor & Francis in Separation Science and Technology on 20 Dec 2017, available online: https://doi.org/10.1080/01496395.2017.1405034. | ||||
Keywords: | Ion exchange; silica-based resin; Purolite S950; cobalt; nickel | ||||
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Institution: | The University of Sheffield | ||||
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Chemical and Biological Engineering (Sheffield) | ||||
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Depositing User: | Symplectic Sheffield | ||||
Date Deposited: | 12 Jan 2018 11:31 | ||||
Last Modified: | 20 Dec 2018 01:38 | ||||
Published Version: | https://doi.org/10.1080/01496395.2017.1405034 | ||||
Status: | Published online | ||||
Publisher: | Taylor & Francis | ||||
Refereed: | Yes | ||||
Identification Number: | https://doi.org/10.1080/01496395.2017.1405034 | ||||
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